搜索结果: 1-15 共查到“大气科学 the kinetics”相关记录21条 . 查询时间(0.062 秒)
Iron dissolution kinetics of mineral dust at low pH during simulated atmospheric processing
mineral dust low pH simulated atmospheric processing
2011/2/25
We investigated the iron (Fe) dissolution kinetics of African (Tibesti) and Asian (Beijing) dust samples at acidic pH with the aim of reproducing the low pH conditions in atmospheric aerosols. The Bei...
Different photolysis kinetics at the surface of frozen freshwater vs. frozen salt solutions
Different photolysis kinetics frozen freshwater frozen salt solutions
2010/11/30
Reactions at air-ice interfaces can proceed at very different rates than those in aqueous solution, due to the unique disordered region at the ice surface known as the quasi-liquid layer (QLL) . The p...
Heterogeneous reactions of carbonyl sulfide on mineral oxides: mechanism and kinetics study
carbonyl sulfide mineral oxides mechanism and kinetics study
2010/11/29
The heterogeneous reactions of carbonyl sulfide (OCS) on the typical mineral oxides in the mineral dust particles were investigated using a Knudsen cell flow reactor and a diffuse reflectance UV-vis s...
Water-soluble SOA from Alkene ozonolysis: composition and droplet activation kinetics inferences from analysis of CCN activity
Water-soluble SOA droplet activation kinetics inferences CCN activity
2010/2/21
Cloud formation characteristics of the water-soluble organic fraction (WSOC) of secondary organic aerosol (SOA) formed from the ozonolysis of alkene hydrocarbons (terpinolene, 1-methlycycloheptene and...
Heterogeneous ozonation kinetics of 4-phenoxyphenol in the presence of photosensitizer
Heterogeneous ozonation kinetics 4-phenoxyphenol photosensitizer
2010/2/21
At the mixing ratio of 60 ppb which corresponds to strongly polluted ozone areas, the first order of decay of 4-phenoxyphenol is k1=9.95×10−6 s−1. At a very high ozone mixing ratio of 6 pp...
Kinetics and mechanisms of heterogeneous reaction of NO2 on CaCO3 surfaces under dry and wet conditions
heterogeneous reaction CaCO3 surfaces dry wet
2010/2/1
With increasing NO2 concentration in the troposphere, the importance of NO2 reaction with mineral dust in the atmosphere needs to be evaluated. Until now, little is known about the reaction of NO2 wit...
Slower CCN growth kinetics of anthropogenic aerosol compared to biogenic aerosol observed at a rural site
CCN growth kinetics anthropogenic aerosol biogenic aerosol
2010/1/18
Growth rates of water droplets were measured with a static diffusion cloud condensation chamber in May–June 2007 at a rural field site in Southern Ontario, Canada, 70 km north of Toronto. The observat...
Sensitivity of polar stratospheric ozone loss to uncertainties in chemical reaction kinetics
polar stratospheric ozone uncertainties chemical reaction kinetics
2009/11/19
The impact and significance of uncertainties in model calculations of stratospheric ozone loss resulting from known uncertainty in chemical kinetics parameters is evaluated in trajectory chemistry sim...
Cloud condensation nuclei measurements in the marine boundary layer of the Eastern Mediterranean: CCN closure and droplet growth kinetics
marine boundary layer Eastern Mediterranean CCN closure droplet growth kinetics
2009/9/27
Measurements of cloud condensation nuclei (CCN) concentrations (cm−3) between 0.2 and 1.0% supersaturation, aerosol size distribution and chemical composition were performed at a remote marine s...
Organic nitrate and secondary organic aerosol yield from NO3 oxidation of β-pinene evaluated using a gas-phase kinetics/aerosol partitioning model
Organic nitrate secondary organic aerosol gas-phase kinetics/aerosol partitioning model
2009/3/13
The yields of organic nitrates and of secondary organic aerosol (SOA) particle formation were measured for the reaction NO3+β-pinene under dry and humid conditions in the atmosphere simulation chamber...
Relating CCN activity, volatility, and droplet growth kinetics of β-caryophyllene secondary organic aerosol
Relating CCN activity kinetics β-caryophyllene secondary organic aerosol
2009/3/13
This study investigates the droplet formation characteristics of secondary organic aerosol (SOA) formed during the ozonolysis of sesquiterpene β-caryophyllene (with and without hydroxyl radicals prese...
Kinetics of the gas-phase reactions of OH radicals with alkanes and cycloalkanes
Kinetics gas-phase reactions OH radicals alkanes cycloalkanes
2009/3/11
The available database concerning rate constants for gas-phase reactions of the hydroxyl (OH) radical with alkanes through early 2003 is presented over the entire temperature range for which measureme...
Ozone decomposition kinetics on alumina: effects of ozone partial pressure, relative humidity and repeated oxidation cycles
Ozone decomposition kinetics alumina ozone partial pressure relative humidity repeated oxidation cycles
2009/3/3
The room temperature kinetics of gas-phase ozone loss via heterogeneous interactions with thin alumina films has been studied in real-time using 254nm absorption spectroscopy to monitor ozone concentr...
Kinetics and mechanism of the uptake of N2O5 on mineral dust at 298 K
Kinetics mechanism N2O5 mineral dust
2009/2/19
The heterogeneous reaction of N2O5 with mineral (Saharan) dust has been studied at T=298 K using a combination of Knudsen and DRIFTS cells for kinetic and product investigations, respectively. The ini...
Kinetics and mechanism of heterogeneous oxidation of sulfur dioxide by ozone on surface of calcium carbonate
Kinetics and mechanism heterogeneous oxidation sulfur dioxide calcium carbonate
2009/1/12
Sulfate particles play a key role in the air quality and the global climate, but the heterogeneous formation mechanism of sulfates on surfaces of atmospheric particles is not well established. Carbona...