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H2{SO}4-silica as an efficient and chemoselective catalyst for the synthesis of acylal from aldehydes under solvent-free conditions
Acylals aldehydes catalysis solvent-free reactions
2010/4/9
A variety of aldehydes react with acetic anhydride in the presence of a catalytic amount of H2SO4-silica to afford the corresponding 1,1-diacetates (acylals) in excellent yields. Ketones are not affec...
Extraction Equilibria of Nicotinic Acid Using Alamine 300/Diluent and Conventional Solvent Systems
Extraction equilibria Nicotinic acid Alamine 300 Modeling
2010/4/22
The distribution of nicotinic acid between water and Alamine 300 (tri-n-octylamine) dissolved in various (proton-donating and -accepting, polar and nonpolar) diluents, and a comparison with the extrac...