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FTIR and Resonance Raman Studies of Nitric Oxide Binding to H93G Cavity Mutants of Myoglobin
Animals Nitric Oxide Imidazoles Myoglobin Enzyme Inhibitors Free Radical Scavengers Spectroscopy, Fourier Transform Infrared Spectrum Analysis, Raman Binding Sites Molecular Structure
2016/5/23
Nitric oxide (NO) binds to the myoglobin (Mb) cavity mutant, H93G, forming either a five- or six-coordinate Fe-NO complex. The H93G mutation eliminates the covalent attachment between the protein and ...
19F NMR of Trifluoroacetyl-Labeled Cysteine Mutants of Myoglobin:Structural Probes of Nitric Oxide Bound to the H93G Cavity Mutant
19F NMR Trifluoroacetyl Cysteine Mutants Myoglobin Nitric Oxide H93G Cavity Mutant
2016/5/23
Nitric oxide (NO) binds to the myoglobin (Mb) cavity mutant, H93G, forming either a 5- or 6-coordinate Fe--NO heme complex. The H93G mutation replaces the proximal histidine of Mb with glycine, allowi...
The H93G Myoglobin Cavity Mutant as a Versatile Template for Modeling Heme Proteins:Ferrous,Ferric,and Ferryl Mixed-Ligand Complexes with Imidazole in the Cavity
copper(II) azomethine imidate crystal structures
2016/5/23
One of the difficulties in preparing accurate ambient-temperature model complexes for heme proteins, particularly in the ferric state, has been the generation of mixed-ligand adducts: complexes with d...
The Role of the Distal and Proximal Protein Environments in Controlling the Ferric Spin State and in Stabilizing Thiolate Ligation in Heme Systems:Thiolate Adducts of the Myoglobin H93G Cavity Mutant
salicylic alcohols hydrogen bonds quantum chemistry
2016/5/23
Recently, heme protein cavity mutants have been engineered in which the proximal coordinating amino acid has been replaced by a smaller, noncoordinating residue leaving a cavity that can be filled by ...
Hydrogen Bonding Modulates Binding of Exogenous Ligands in a Myoglobin Proximal Cavity Mutant
Alanine Amino Acid Substitution Animals Binding Sites Glycine Histidine Hydrogen Bonding Imidazoles Ligands Macromolecular Substances Metmyoglobin Models, Chemical Mutagenesis, Insertional Myoglobin Nitric Oxide Nuclear Magnetic Resonance,Biomolecular Protons Serine Threonine Whales
2016/5/23
In the sperm whale myoglobin mutant H93G, the proximal histidine is replaced by glycine, leaving a cavity in which exogenous imidazole can bind and ligate the heme iron (Barrick, D. (1994) Biochemistr...
Assignment of the Heme Axial Ligand(s) for the Ferric Myoglobin (H93G) and Heme Oxygenase (H25A) Cavity Mutants as Oxygen Donors Using Magnetic Circular Dichroism
Alanine Animals Circular Dichroism Electron Transport Glycine Heme Heme Oxygenase (Decyclizing) Heme Oxygenase (Decyclizing) Histidine Humans Hydrogen-Ion Concentration Iron Ligands Mutagenesis, Site-Directed Myoglobin Myoglobin Oxygen Spectrophotometry,Ultraviolet Spectrum Analysis, Raman Titrimetry Whales
2016/5/23
UV-visible absorption and magnetic circular dichroism (MCD) data are reported for the cavity mutants of sperm whale H93G myoglobin and human H25A heme oxygenase in their ferric states at 4 degreesC. D...
Trans Effects in Nitric Oxide Binding to Myoglobin Cavity Mutant H93G
biology and medicine, basic studies nitric oxide biochemistry heme histidine imidazoles ligands mutants myoglobin proteins
2016/5/23
When nitric oxide (NO) binds to heme proteins, it exerts a repulsive trans effect on the proximal ligand, resulting in weakening or rupture of the proximal ligand-iron bond. The general question of wh...
Modulation of Protein Function by Exogenous Ligands in Protein Cavities:CO Binding to a Myoglobin Cavity Mutant Containing Unnatural Proximal Ligands
Animals Binding Sites Carbon Monoxide Cloning, Molecular Escherichia coli Heme Kinetics Ligands Magnetic Resonance Spectroscopy Mutagenesis, Site-Directed Myoglobin Myoglobin Point Mutation Protein Conformation ecombinant Proteins Recombinant Proteins Spectroscopy,Fourier Transform Infrared Valine Whales
2016/5/23
A variety of heterocyclic ligands can be exchanged into the proximal cavity of sperm whale myoglobin mutant H93G, providing a simple method for introduction of the equivalent of unnatural amino acid s...
Characterizing entanglement of an artificial atom and a cavity cat state with Bell’s inequality
Characterizing entanglement cavity cat state Bell’s inequality
2016/1/22
The Schrodinger’s cat thought experiment highlights the counterintuitive concept of entan-glement in macroscopically distinguishable systems. The hallmark of entanglement is the detection of strong co...
Majority dynamics on trees and the dynamic cavity method
Voters independent distribution random variables the initialization
2015/8/20
An elector sits on each vertex of an in nite tree of degree k, and has to decide between two alternatives.At each time step, each elector switches to the opinion of the majority of her neighbors. We a...
Autonomous Underwater Vehicle exploration of the Ocean cavity Beneath an Antarctic ice Shelf
Underwater Vehicle Ocean
2015/7/15
in recent years, mass loss from the Antarctic
ice Sheet has contributed nearly 0.5 mm yr–1
to global mean sea level rise, about one-sixth of
the current rate (church et al., 2011). Around
...
FUNCTIONAL AND COMPARATIVE MORPHOLOGY OF THE NASAL CAVITY IN PHYLLOSTOMID BATS
olfaction airflow phyllostomid nasal cavity turbinate
2014/12/18
The functional morphology and evolution of the nasal cavity is poorly understood. The New World Leaf-nosed bats of the family Phyllostomidae are an excellent group of mammals in which to study the evo...
Comparison of water isotope analysis between cavity ring-down spectroscopy and isotope ratio mass spectrometry
oxygen isotopes hydrogen isotopes water isotope ratio mass spectrometry (IRMS) cavity ring-down spectroscopy (CRDS)
2017/4/10
δD and δ18O of natural waters with δ18O ranging from –24 to –6‰ were measured using a cavity ring-down spectroscopy
(CRDS) in order to confirm that the CRDS method can be an alternative to convention...
Modelling the Cavity of Continuous Chemical Lasers (CCLs) Using Matlab Applications
Chemical Laser Spectroscopy Vibrational Rotational Processes Lasers Cavity
2013/1/30
The subject that concerns us in this work is the numerical simulation and optimal control of equilibrium of the continuous chemical lasers (CCLs). Laser Chemistry: Spectroscopy, Dynamics and Applicati...
Cavity-meidated collisionless sympathetic cooling of molecules with atoms
Cavity-meidated collisionless sympathetic molecules atoms Atomic Physics
2012/5/29
Cooling a range of molecules to ultracold temperatures (<1 mK) is a difficult but important challenge in molecular physics and chemistry. Collective cavity cooling of molecules is a promising method t...