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Vibrational Stark Spectroscopy of NO Bound to Heme:Effects of Protein Electrostatic Fields on the NO Stretch Frequency
rare earth alloys X-ray diffraction crystal structure phase diagram
2016/5/23
The vibrational Stark effect measures the effect of an external electric field on the vibrational (IR) spectrum of a molecule. This technique gives quantitative information on the sensitivity of a vib...
Stark Effect Spectroscopy of the Heme Charge Transfer Bands of Deoxymyoglobin
materials science electronic structure oxygen compounds myoglobin charge transport stark effect absorption spectra spectroscopy heme protoporphyrins
2016/5/23
We report the Stark spectra of the Soret, Q, and charge-transfer bands of deoxymyoglobin. The data show that band III has charge-transfer character but that the magnitude of the charge displacement is...