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Site-Specific Conversion of Cysteine Thiols into Thiocyanate Creates an IR Probe for Electric Fields in Proteins
food packaging perfluorinated dietary intake human exposure
2016/5/24
The nitrile stretching mode of the thiocyanate moiety is a nearly ideal probe for measuring the local electric field arising from the organized environment of the interior of a protein. Nitriles were ...
A New and Convenient Method of Generating Alkyl Isocyanates from Alcohols, Thiols, and Trimethylsilyl Ethers Using a 2,4,6-Trichloro[1,3,5] Triazine/n-Bu4NOCN
2,4,6-Trichloro[1,3,5] triazine (TT) alcohol thiol trimethylsilyl ether alkyl isocyanate
2010/4/19
Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[1,3,5] triazine/n-Bu4NOCN in acetonitrile. This method is hi...
Distribution of the thiols glutathione and 3-mercaptopropionic acid in Connecticut lakes
Distribution of the thiols glutathione -mercaptopropionic acid
2014/5/5
The spatiotemporal chemical characteristics of the water column in Linsley Pond, a freshwater lake in
Connecticut, were studied from just before its stratification in April through the fall turnover ...
Selective Oxidation of Thiols to Disulfides Catalyzed by Iron(III) -- Tetra Phenyl Porphyrin Using Urea-Hydrogen Peroxide as Oxidizing Reagent
Thiols Fe (TPP) Cl Urea hydrogen peroxide disulfides
2010/4/20
Oxidation of thiols to disulfides catalyzed by iron(III) -- tetra phenyl prophyrin Fe (TPP)Cl was investigated using urea-hydrogen peroxide adduct (UHP) as an oxidant in methanol as a solvent.
Effects of copper, cadmium, and zinc on the production and exudation of thiols by Emiliania huxleyi
copper cadmium zinc production exudation thiols Emiliania huxleyi
2014/5/9
Cultures of the ubiquitous coccolithophore Emiliania huxleyi grown at field-relevant fixed free ion concentrations of Cu, Cd, and Zn exude a broad array of thiols, some of which increase with increasi...
Response of nonprotein thiols to copper stress and extracellular release of glutathione in the diatom Thalassiosira weissflogii
non protein thiols copper stress extracellular release glutathione diatom Thalassiosira weissflogii
2014/5/9
We studied the dynamic changes of cellular thiols and the extracellular release of glutathione (GSH) during growth of the marine diatom Thalassiosira weissflogii under varying levels of copper (Cu) ad...
Thiols in wetland interstitial waters and their role in mercury and methylmercury speciation
wetland interstitial waters their role in mercury methylmercury speciation
2014/5/19
Organic sulfhydryl compounds, or thiols, are ligands that strongly complex class B metals such as Hg and methylmercury (MeHg). We determined the concentration profiles of five low-molecular-weight thi...
Novel copper-binding and nitrogen-rich thiols produced and exuded by Emiliania huxleyi
Novel copper-binding nitrogen-rich thiols produced
2014/5/19
In surface seawater, dissolved copper (Cu) is predominantly bound by a small pool of strong ligands, with further
complexation by a larger pool of weaker ligands. Although the chemical structure of b...