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The effects of chemical reduction of structural Fe3+ in nontronite SWa-1 (ferruginous smectite) on intervalence electron transfer (IT) and magnetic exchange were investigated. Visible absorption spect...
A new approach to the interpretation of Mössbauer spectra of Fe3+-phyllosilicates having vacant trans-octahedra is based on (1) crystal structure simulation methods that allow for the size and th...
The effects of reduction and reoxidation of octahedral Fe3+ on the exchange of structural hydrogen in nontronite were determined using tritium (3H) as a label element. The uptake of H from the surroun...
Abstract: The 57Fe Mössbauer spectra of untreated, Ca- and K-saturated nontronite from Garfield, Washington, were measured. The spectrum of the untreated sample was computer-fitted to 8 peaks def...
Smectite close to the pure Fe end member of the nontronite-beidellite series was found in the fine clay separated from a 354-cm deep sediment core in the southwestern Pacific Basin. The mineral has a ...
Infrared spectra of nontronite reveal shifts to lower wave, number in peaks located at 3570, 1030, and 821 cm−1, which are assigned to vibrational modes for O-H stretching, Si-Ob (basal oxygens)...
Mossbauer and i.r. spectra of a series of nontronites show that Fe3+ and Al3+ are distributed between tetrahedral and octahedral sites. The M鰏sbauer results have reaffirmed the occupation by Fe3+ of o...
Garnierite from the Tocantins Complex at Niquelandia, Brazil, is a 15侌, dioctahedral clay mineral, nickeliferous nontronite. The principal octahedral cations are Fe3+, Al and Ni. The ferric state of t...
The basal spacings of long chain n-alkanol complexes of nontronite saturated with Li+, K+ Mg2+, Ca2+, Sr2+ and Ba2+ were measured for temperatures increasing from −70°C up to 130°C. With rising ...
A smectite rich in ferrous iron and low in aluminum occurs abundantly in the Red Sea Geothermal Deposits, and appear to be forming at present.Chemical analyses and Mossbauer spectra indicate the miner...

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