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The Schiff base octaazamacrocyclic ligands derived from primary diamines and 3,6-dimethyl/diphenyl-4,5-diazaocta-3,5-diene-2,7-dione, and their binuclear complexes [M2LCl4]Cl2 [M = Cr(III), Fe(III), C...
在真空条件下研究了Cp2Fe在HY沸石表面的接枝反应,并用原位FTIR、ICP、XRD、TPD-MS和UV-Vis DRS等方法对接枝产物的组成、结构及性质进行了表征。结果表明,在低于423 K的温度下,Cp2Fe可以强吸附在沸石的超笼内,并被氧化为Cp2Fe+阳离子;当在423 K长时间加热时,Cp2Fe+可与超笼表面的酸性中心发生化学反应,脱除一个环戊二烯基团,在沸石超笼形成“半三明治”环戊二...
Dechlorination of hexachlorobenzene (HCB) was achieved by a mixture of commercial CaO and a-Fe2O3 (CaO/a-Fe2O3) in closed systems at temperatures of 300 C and 350 C, which exhibited a synergic effec...
Oxidation of thiols to disulfides catalyzed by iron(III) -- tetra phenyl prophyrin Fe (TPP)Cl was investigated using urea-hydrogen peroxide adduct (UHP) as an oxidant in methanol as a solvent.
Within the framework of the International Atomic Energy Agency (IAEA) Analytical Quality Control Service (AQCS) Chemistry Unit a research program was initiated for the identification of trace elements...
A new spectrophotometric method is developed for the determination of Fe(II) with 5-nitro-6-amino-1,10-phenanthroline (NAF). In this work, the effect of factors such as pH, amount of reagent (NAF), re...
The use of nicotinamide ``3-pyridineamide'' as an iron corrosion inhibitor was tested in aerated aqueous solutions of NaCl and Na2SO4 for different pH values. Polarization resistance (Rp) measurements...
In this work, the corrosion behavior of iron and aluminum was investigated in 0.1 M NaCl solutions with an initial pH value of 8 and containing various concentrations (0, 30, 150, 300 ppm) of benzoic ...
Determination of Manganese and Iron in Magmatic Rocks After Ultrasonic Leaching by flame AAS.
Abstract. Nanogram quantities of nickel were removed from 1 L samples of dilute aqueous solutions by coflotation. A mixture of hydrated iron(III) oxide (Fe2O3\( \cdot \)xH2O) and iron(III) hexamethyle...
The current-potential values were measured with iron or aluminium electrodes in solutions of 3.5% NaCl containing 30, 150, 300 ppm linear alkylbenzene (LAB) and detergents (LAS) at pH8. Polarization r...
The effect of phosphate ions on the corrosion of iron in sulphate solutions at different temperatures (293 K, 313 K, 333 K and 353 K) and at different pH (pH=2.1, 7.2 and 12.3) values was investigated...

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