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Synthesis and crystal structure of a novel multimodal ligand, 6,6'-bis(2-(di(pyridin-2-yl)methylene)-1-methylhydrazinyl)-2,2'-bipyridine and its copper(I) complex, {[Cu3L2](PF6)3?3H2O} (1)
Bipyridine derivatives hydrazone dipyridyl ketone metal complexes
2010/10/19
The single crystal X-ray structure of the novel multimodal ligand 6,6’-bis(2-(di(pyridin-2-yl)methylene)-1-methylhydrazinyl)-2,2’-bipyridine, C34H28N10 (L), was determined at 120 (2) K. The ligand pos...
Synthesis and Characterizations of Some New 2,4-Dihydro-[1,2,4]-triazol-3-one Derivatives and X-Ray Crystal Structures of 4-(3-Phenyl allidene amino)-5-thiophen-2-yl-methyl-2,4-dihydro-[1,2,4]triazol-3-one
1,2,4-Triazole aldehydes ethyl bromoacetate bromo acetophenone
2010/10/19
Compounds 2 were synthesised via the reaction of 4-amino-5-thiophen-2-yl-methyl-2,4-dihydro-[1,2,4]-triazol-3-one (1) with aldehydes. Compounds 3 and 4 were obtained from compounds 2 with bromo acetop...
Synthesis, Spectroscopic Characterization, Mass Spectrometry and Crystal Structure of N-{[(4-bromophenyl) amino]carbonothioyl}benzamide
Thiourea derivative X-ray structure determination mass fragmentation
2010/10/19
N-{[(4-bromophenyl)amino]carbonothioyl}benzamide was synthesized and characterized by IR, 1 H- and 13C-NMR, mass spectrometry, and elemental analysis. The crystal structure was determined from single ...
Bromodimethylsulfonium Bromide/ Tetrabutylammonium Nitrite: An Efficient Catalyst Mixture for the Nitration of Phenols
Bromodimethylsulfonium bromide nitration, nitrophenol tetrabutylammonium nitrite
2010/10/19
Nitrophenols were obtained via direct nitration of phenols with tetrabutylammonium nitrite in the presence of bromodimethylsulfonium bromide at room temperature in high yields under aprotic conditions...
Synthesis and super-swelling behavior of a novel low salt-sensitive protein-based superabsorbent hydrogel: collagen-g-poly(AMPS)
Collagen hydrogel swelling 2-acrylamido-2-methylpropanesulfonic acid
2010/10/19
Superabsorbent polymers are obtained by the graft copolymerization of 2-acrylamido-2-methylpropanesulfonic acid (AMPS) monomer onto collagen, using ammonium persulfate as a free radical initiator in t...
Co(III) Catalysed Asymmetric Ring-Opening of Epichlorohydrin by Salicylaldehyde Derivatives: Reversal of Enantioselectivity and Rate Acceleration on Addition of AlCl3
Asymmetric catalysis salicylaldehyde Co(III) salen
2010/10/19
Using asymmetric Cobalt(III) salen catalysts, the ring-opening of epichlorohydrin by 2,3-dihydroxybenzaldehyde and 2,4- dihydroxybenzaldehyde was found to occur at the phenolic groups most distant fro...
Synthesis and characterization of novel triazol compounds containing a thiophen ring as potential antifungal agents and the structure of 2-(2-hydroxy-2-p-tolyethyl)-5-(thiophen-2-ylmethyl)- 4-(4H-1,2,4-triazol-4-yl)-2H-1,2,4-triazol-3(4H)-one
Synthesis 1,2,4-triazole-3-one NaBH4 LiAlH4 antimicrobial activity
2010/10/18
A series of new 4-(3,5-disubstitue-4H-1,2,4-triazol-4-yl)- 5-(thiophen-2-yl-methyl)-2H-1,2,4-triazol-3(4H)-ones (3a-c) were obtained by reaction N'-1-ethoxy-2-thiophen-2-yl-ethylydene hydrazino carbox...
Heterocyclic synthesis using nitrilimines: part 14. Synthesis of new pyrazole derivatives
Nitrilimines 1,3-dipolar cycloaddition phthalides pyrazoles
2010/10/18
A new series of 1,3,4,5-tetrasubstituted pyrazoles have been synthesized by the 1,3-dipolar cycloaddition of suitable nitrilimines to 3-propylidene and 3-benzylidene-phthalide. Both analytical and spe...
Synthesis and antimicrobial activities of some new biheterocyclic compounds containing 1,2,4-triazol-3-one and 1,3,4-thiadiazole moieties
1,2,4-triazol-3-one 5-thioxo-1,2,4-triazole
2010/10/18
2-(4-Amino-3-(4-chlorophenyl)-5-oxo-4,5--dihydro-1H-1,2,4-triazol- 1-yl)-N'-[(2,6-dihalogenophenyl)-methylene]acetohydrazides (3a,b) was obtained via the formation of 2-(4-amino-3-(4-chlorophenyl)-5-o...
Synthesis and characterization of gold nanoparticles supported on zinc oxide via the deposition-precipitation method
Au nanoparticles ZnO nanorods deposition-precipitation
2010/10/19
Gold nanoparticles supported on zinc oxide nanoparticles were synthesized at several pH levels via the deposition-precipitation (DP) method. The effects of pH on gold loading, particle size, and parti...
A calorimetric study of the interaction of silver ions with jack bean urease
Urease silver ion isothermal titration calorimetry
2010/10/19
A thermodynamic study of silver ions by jack bean urease (JBU) was carried out at 2 temperatures, 27 and 37 °C, in Tris buffer (30 mM; pH 7.0) using isothermal titration calorimetry (ITC). There was a...
Friedel-Crafts acylation of arenes with carboxylic acids using silica gel supported AlCl3
Acylation aluminium trichloride ketones silica gel
2010/10/19
Aromatic compounds react smoothly with carboxylic acids in the presence of silica gel supported aluminium trichloride to afford the corresponding ketones with high regioselectivity in high to excellen...
Sulfonic acid-functionalized silica: a remarkably efficient heterogeneous reusable catalyst for the one-pot synthesis of 1,4-dihydropyridines
1,4-Dihydropyridine b-dicarbonyl compounds solid acid SiO2-R-SO3H
2010/10/19
An efficient one-pot method for the synthesis of 1,4-dihydropyridines from b-dicarbonyl compounds, aldehyde, and ammonium acetate is reported using sulfonic acid-functionalized silica at 90 °C under s...
Synthesis and characterisation of vanadium(III) complexes of biphenylphenols
Vanadium(III) complexes biphenylphenols magnetic study
2010/10/19
The vanadium(III) complexes of composition [VCl3-n(OAr1,2)n.(THF)2] (OAr1 = 2-phenylphenoxo and OAr2 = 4-phenylphenoxo, THF = tetrahydrofuran; n = 1 /to 3) were prepared by in situ reaction of VCl3.(T...
Preparation of polystyrene/montmorillonite nanocomposites: optimization by response surface methodology (RSM)
Montmorillonite organoclays polymer polystyrene
2010/10/19
Preparation of polystyrene (PS)-montmorillonite nanocomposites was carried out in 3 steps: purification and determination of the cation exchange capacity (CEC) of clay, synthesis of organoclay, and pr...