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【兴大报告632】A Personal Account on the Total Synthesis for Structural Validation of Natural Glycans and Glycoconjugates（图）
Natural Glycans Glycoconjugates Structural Validation
2023/6/20
报告人：俞飚 教授
中国科学院
Total Synthesis of (±)-Decursivine and (±)-Serotobenine: A Witkop Photocyclization/Elimination/O-Michael Addition Cascade Approach
Total Synthesis of (±) Decursivine and (±)-Serotobenine A Witkop Photocyclization/Elimination/O-Michael Addition Cascade Approach
2012/7/3
Decursivine和Serotobenine是一类具有苯并二氢呋喃，吲哚并八元内酰胺多环体系的吲哚生物碱，分别具有抗疟疾及广泛的抗菌活性，其良好的生物活性和独特新颖的结构，引起了合成化学家的关注。其中Michael A. Kerr小组以18步3%的总收率首次完成了(±)-Decursivine的全合成，Tohru Fukuyama小组以24步8%的总收率首次完成了(-)-Serotobenin...
Implementation and Innovation in Total Synthesis
organic chemistry total synthesis Philosophy of applied science
2008/4/14
This paper investigates how understanding the theory of organic chemistry facilitates the total synthesis of organic compounds. After locating the philosophical significance of this question within th...