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Abstract: Molecular dynamics computer simulations were used to study methanol molecules confined between the layers of 2:1 phyllosilicates. The model systems are based on natural Ca- and Na-rich montm...
The Cl NMR spectroscopy of Cl -intercalated hydrotalcite and the Ca-aluminate hydrate, the presence of hydrocalumite (Friedel°Os salt) demonstrates dynamical behavior of interlayer C dynamical orde...
Abstract: Monte Carlo simulations based on tested water-water, cation-water, and water-clay potential functions were applied to calculate radial distribution functions for O-O, O-H and H-H spatial cor...
Abstract: The structure of the interlayer cation-water system in La-vermiculite with a unit cell of a = 5.33(5), b = 9.18(6), c = 15.13(9) 侌 and 兝 = 96.82(7)亱 has been determined in space group C2/m. ...
Dehydration of Ca- and Mg-exchanged montmorillonite was studied along H20 iso- chores in the hydrothermal diamond-anvil cell by in situ X-ray diffraction using a syn- chrotron radiation source. At-r...
The in-depth perturbation of vicinal water by the surfaces of montmorillonite layers was investigated by relating the swelling pressure, Π, of the montmorillonite layers to the H-O-H bending frequency...
Abstract: The compositions, fabrics and structures of authigenic minerals that formed recently from silicic volcanic ash layers from a 1300-meter sediment column obtained at ODP Site 808 of the Nankai...
Monte Carlo (MC) simulations of interlayer molecular structure in monolayer hydrates of Na-saturated Wyoming-type montmorillonites and vermiculite were performed. Detailed comparison of the stimulatio...
Monte Carlo (MC) simulations of molecular structure in the interlayers of 2:1 Na-saturated clay minerals were performed to address several important simulation methodological issues. Investigation was...
A synergistic mechanism for the retention of organic and inorganic pollutants in clays is discussed in this paper. The mechanism of adsorption of cis- or trans-1,2-dichloroethylene vapor (CDE or TDE, ...
Abstract: Investigation of mixed-layer illite/smectites with far-infrared (FIR) spectroscopy indicates the presence of torsional mode absorption bands associated with interlayer fixed-K sites. By cont...
The dehydration and migration of the interlayer cation of the synthetic beidellite Na0.7Al4.7Si7.3O20-(OH)4·nH2O, were studied with solid-state 23Na and 27Al MAS-NMR, heating stage XRD, and thermograv...
The dehydration reaction of kerolite was investigated using high-pressure differential thermal analysis at pressures as high as 600 bars. The peak associated with the dehydration is broad, suggesting ...
Infrared and Mössbauer spectroscopic studies were made on hydrotalcite-like materials, Mg6Al2(OH)16(NO3)2·4H2O, anion exchanged in aqueous solution of K3Fe(CN)6, K4Fe(CN)6·3H2O, or Na2Fe(CN)5NO·2...
A new type of environmental chamber for X-ray diffraction was designed that could sustain elevated, internal pressures of nitrogen or any other gas under oxygen-free conditions and that allowed the po...

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