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Aluminum-rich titanites [Ca(Ti,Al)(O,F)SiO ] with X > 0.53 [X = Al/(Al+Ti)], including the pure end-member CaAlFSiOwere synthesized for the first time in a high-pressure experimental was determined...
Our recent paper noted that °∞some of the existing [M?ssbauer] studies (e.g., Fuchs et al. 1995) should be discounted due to th fact that peak widths are less than the theoretical minimum imposed by ...
TitaniteofvariableAlandFcontentwasfoundingranulite-toamphibolite-facies calcsilicatesinCentralDronningMaudLand,Antarctica.ThehighestobservedAlcon- tentcorrespondstoanX [ Al/(Al Ti)]of0.53.Previousl...
Radiogenic impurities of 400 to 800 ppm U and Th in titanite, CaTiSiO5, lead to mod-erate radiation damage (?.5 3 10 18 a-decay events/g) and therefore to partial amorphi-zation (?0%). Powder X-ray di...
For iron-rich compositions, reactions among titanite, clinopyroxene, olivine, quartz,magnetite, and ilmenite can constrain the conditions under which common rocks form.Phase equilibrium experiments in...
Single crystals of MnSiO(SiO4) with the titanite structure together with MnSiO3 clino-pyroxene were synthesized from a MnO-SiO2 oxide mixture at 10008 C and 9.2 GPa in a multi-anvil press. The crystal...
Theenthalpyofdropsolutionofaquicklyquenched,clear,titaniteglasssampleandseveralsynthetic,polycrystalline,sampleswasmeasuredinaCalvet-typecalorimeterin2PbO!/ O solventat702C.Theenthalpyofformationofst...
Unit-cellparametersofsynthetic,end-membertitanite(CaTiOSiO )criticallydependonthesynthesisconditions,asisshownforstudiesreportedintheliteratureandfornew samplesreportedhere.Ourstudysuggeststhatphase-...
X-raydiffractionrockingcurvesoftitanite,CaTiSiO ,weremeasuredusinganovelhigh-resolutiondiffractometer.ThreeBraggre?ectionswererecordedasafunctionoftemperatureandtheirpro?lesanalyzedintermsofaGaussianB...
Theatomicarrangementofanaturalrare-earth-richtitaniteandtwosyntheticrare-earth- dopedtitaniteshavebeenre?nedinspacegroup A2/a, andtheatomicarrangementofanundoped P2 /a synthetictitanitewasalsore?ned...
The coordination environments of Ti in two fully metamict zirconolite samples and two partially metamict titanite samples were determined using high-resolution, X-ray absorp- tion near-edge structur...
We report the direct experimental observation of a structural anomaly near 825 K insynthetic and natural titanite samples by high-temperature, hard-mode infrared spectros-copy. The anomaly in titanite...
Apressure-induced phase transition was observed in a sample of synthetic titanite (CaTiOSi04). The high-pressure structure was refined in space group A21a [a = 6.8912(3), b = 8.6234(3), c = 6.4065(3)...

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