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Nuclear Magnetic Resonance (NMR) Study of Cd2+ Sorption on Montmorillonite
Adsorption Cadmium Montmorillonite Nuclear Magnetic Resonance
2011/12/8
Abstract: 113Cd solid-state nuclear magnetic resonance (NMR) was used to identify possible Cd2+ adsorption sites in montmorillonite. The montmorillonite was treated with 0.1 and 1 M CdCl2 aqueous solu...
Si,Al ordering in the double-ring silicate armenite, BaCa2Al6Si9O30?H2O: A single-crystal X-ray and 29Si MAS NMR study
BaCa2Al6Si9O30?H2O single-crystal
2012/3/30
29The SiMASNMRspectrumofarmenitefromWasenalp(Valais,Switzerland)indicates
completeSi,Alordering.Thesamechemicalshifts(82.3,95.0,and101.8ppm)were
alsomeasuredforarmenitefromRe!migny(Quebec,Canada),ho...
Structure and dynamics of magnesium in silicate melts: A high-temperature 25Mg NMR study
Structure dynamics magnesium silicate melts high-temperature
2012/4/1
25Mg NMR spectra for several silicate and aluminosilicate melts were obtained from 1000–1470 8C. The peaks are initially very broad, but narrow with increasing temperature to near 500 Hz at the highes...
Cation mixing in natural MgAl2O4 spinel: A high-temperature 27Al NMR study
Cation mixing MgAl2O4 spinel high-temperature 27Al NMR study
2012/4/6
ThepositionaldisorderofMg andAl cationsbetweenthetetrahedralandoctahedralsitesinnaturalMgAlO spinelhasbeeninvestigatedby AlMASNMRatroomtem-2 427peratureandin-situhigh-temperatureAlNMRspectroscopyupto1...
Si-Al ordering in leucite-group minerals and ion-exchanged analogues: An MAS NMR study
Si-Al leucite-group minerals ion-exchanged analogues MAS NMR study
2012/4/6
Twoseriesofleucitegroupmaterials,withK,Rb,andCsasextra-frameworkcations,havebeensynthesizedbyionexchangefromanaturalwell-orderedanalciteandanatural29 27disorderedleucite.Siand AlMASNMRdatafortheanalci...
NMR Study of Dynamics and Evolution of Guest Molecules in Kaolinite/Dimethyl Sulfoxide Intercalation Compound
2H NMR 13C NMR Dimethyl Sulfoxide Intercalation Compound Kaolinite Layered Silicate
2011/12/22
Abstract: Motion of the guest molecules in kaolinite/dimethyl sulfoxide (DMSO) intercalation compounds Al2Si2O5(OH)4?CH3)2SO has been studied by means of solid-state nuclear magnetic resonance (NMR) i...
MAS NMR study of pentacoordinated magnesium in grandidierite
MAS NMR study pentacoordinated magnesium grandidierite
2012/4/5
The11.7T Mg, Al, Si,and BMASNMRspectraarereportedforwell-charac-terizedgrandidierite,(Mg,Fe)AlSiBO ,whichcontainsbothAlandMgin?vefoldcoor-dinationwithoxygen.TheMgspectrumisthe?rsttobereportedfor Mg,an...
Protons in the magnesium phosphates phosphoellenbergerite and holtedahlite: An IR and NMR study
Protons magnesium phosphates phosphoellenbergerite holtedahlite IR and NMR study
2012/4/5
Two structurally related magnesium phosphates, phosphoellenbergerite (P63mc) and holtedahlite (P63), have been investigated using a combination ofhigh-frequency IR and lH MAS,31p MAS,and 31p CPMASNMR ...
2H NMR spectra of synthetic deuterated kaolinite have been collected in the temperature range from 150 K to 350 K. Hydroxyl groups show a Pake doublet pattern with an asymmetry factor of 0. They are a...
The Interlayer Collapse during Dehydration of Synthetic Na0.7-Beidellite: A 23Na Solid-State Magic-Angle Spinning NMR Study
Beidellite Dehydration Interlayer collapse 23Na MAS-NMR
2011/12/31
The dehydration and migration of the interlayer cation of the synthetic beidellite Na0.7Al4.7Si7.3O20-(OH)4·nH2O, were studied with solid-state 23Na and 27Al MAS-NMR, heating stage XRD, and thermograv...
19F MAS-NMR Study of Structural Fluorine in Some Natural and Synthetic 2:1 Layer Silicates
Clay minerals 19F MAS-NMR Fluorine Layer silicates Silicates Smectites
2011/12/30
High-resolution solid-state, fluorine-19, magic-angle spinning-nuclear magnetic resonance spectroscopy (MAS-NMR) was used to study natural and synthetic fluorinated 2:1 layer silicates of known compos...
A Pulsed NMR Study of the Interfacial Water of a Disperse Suspension of Boehmite
NMR Study Interfacial Water Disperse Suspension Boehmite
2011/11/16
A model is presented for interpreting the observed nuclear spin relaxation of the protons in the water molecules of the dispersing phase in terms of the modification of molecular motion in the solid-l...