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Adsorption of n-Aliphatic Alcohols from Dilute Aqueous Solutions on RNH3-Montmorillonites. III. Interlamellar Aggregation of the Adsorbate
Adsorption Alcohol Alkylammonium cations Intercalation Micellization Montmorillonire
2012/2/2
The large amount of water in the interlamellar space of alkylammonium montmorillonites in aqueous solutions is not fixed by intercalated hexanol or octanol. The hydration of the NH3+-group and the fil...
Reactions of Alcohols with Alkenes over an Aluminum-Exchanged Montmorillonite
Alcohol Alkene Aluminum Catalyst Montmorillonite
2012/2/6
The reaction of 2-methyl pent-2-ene with primary alcohols (C1-C18) at 95°C over an Al-montmorillonite gave yields of 20–90% of ethers of the type R-O-C(CH3)2C3H7. Lower yields were produced if seconda...
The Adsorption of n-Aliphatic Alcohols from Dilute Aqueous Solutions on RNH3-Montmorillonites. II. Interlamellar Association of the Adsorbate
Alcohol adsorption Alkylammonium clays Intercalates Montmorillonite
2012/2/10
The adsorption of butanol, hexanol, and octanol on alkylammonium montmorillonites of different chain length is similar to the distribution of alcohol between an organic solvent and water in bulk solut...
The Adsorption of N-Aliphatic Alcohols from Dilute Aqueous Solutions on RNH3-Montmorillonites. Part I. Distribution at Infinite Dilution
Adsorption Alkylammonium Butanol Hexanol Interlayer Octanol
2012/2/10
The adsorption of butanol, hexanol, and octanol on alkylammonium clays of different chain length is studied. The adsorption at infinite dilution compares to the distribution of alcohol between alkane ...
Use of Long-Spacing Alcohols and Alkanes for Calibration of Long Spacings from Layer Silicates, Particularly Clay Minerals
Long-Spacing Alcohols Alkanes Calibration Long Spacings Layer Silicates Particularly Clay Minerals
2012/2/15
Lattice spacings of layer silicates, particularly clay minerals, may exceed 20 Å. The errors in measuring lattice spacings increase rapidly for spacings greater than about 10 Å and diffrac...