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利用高分辨弱电场加速型光解碎片平动能谱仪,对CF3I在238 nm的光解动力学进行了研究.结果表明,来自3Q0平行跃迁的I*通道[CF3I(X)→CF3I(3Q0)→CF3(ν1,ν2)+I*],信号最强,并可以分辨出碎片CF3(ν1,ν2)的振动峰.通过对峰间距的分析,可以基本分辨出同时具有CF3碎片的振动波带CF3(ν1,ν2=0)与CF3(ν1,ν2=1).其中ν1 =701 cm-1为对称...
Potential impact of iodinated replacement compounds CF3I and CH3I on atmospheric ozone: a three-dimensional modeling study
iodinated replacement compounds CF3I and CH3I atmospheric ozone
2010/11/3
The concept of Ozone Depletion Potentials (ODPs) is extensively used in policy considerations related to concerns about the effects of various halocarbons and other gases on stratospheric ozone. Many ...
Potential impacts of CF3I on ozone as a replacement for CF3Br in aircraft applications
CF3I ozone CF3Br aircraft applications
2009/1/15
Iodotrifluoromethane (CF3I) has been considered to be a candidate replacement for bromotrifluoromethane (CF3Br), which is used in aircraft for fuel inerting and for fire fighting. In this study, the c...
CF3I在强红外场下的多光子解离
多光子解离 强红外场 CF3I
2010/1/22
本文用TEA CO_2激光9.6R(14)支作激发光源, 富里叶变换红外光谱仪作分析手段, NO, O_2作CF_3自由基的捕捉剂, 研究了CF_3I红外多光子解离的动力学。
实验发现, O_2和NO均可用来捕捉CF_3I的红外光解产物CF_3自由基。从对CF_3I的红外多光子解离率与外加气体压力的变化关系的研究, 以及CF_3I红外多光子吸收的测量, 揭示出该分子在受红外激光激发时, 具有小分...