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不加无机强碱，在纯有机胺体系中合成了小晶粒offretite沸石，并采用XRD、SEM、FT-IR以及苯与丙烯烷基化制异丙苯探针反应对典型样品进行了结构性能表征。结果表明，采用四乙基氢氧化铵TEAOH与四甲基溴化铵TMABr为双模板剂时，TEAOH的量对合成产物影响很大，而TMABr的量增大容易导致生成Beta沸石。所合成的offretite沸石在苯与丙烯烷基化制异丙苯反应中活性和选择性较高。
Crystal structure-crystal chemistry relationships in the zeolites erionite and offretite
Crystal structure-crystal chemistry relationships zeolites erionite offretite
2012/3/31
This study clarifies the crystal structure variations and relationships in the zeolites eri-onite and offretite. The crystal structure analyses used Rietveld analysis of X-ray powder diffraction data,...
Crystal chemistry of the zeolites erionite and offretite
Crystal chemistry zeolites erionite offretite
2012/3/31
Many known occurrences of the zeolites erionite and offretite have been characterized by electron probe microanalysis, X-ray powder diffraction, and optical microscopy. For the first time, a substanti...